Smart polymers driven by multiple and tunable hydrogen bonds for intact phosphoprotein enrichment
نویسندگان
چکیده
منابع مشابه
Supramolecular polymers with tunable topologies via hierarchical coordination-driven self-assembly and hydrogen bonding interfaces.
A powerful strategy to obtain complex supramolecular materials is the bottom-up construction of noncovalently bound materials by hierarchical self-assembly. This assembly process involves stepwise, uniform increases to the architectural complexity of a substrate, starting from discrete precursors and growing in dimensionality through controlled reactivity to a final product. Herein, two orthogo...
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Photocatalytic hydrogen production from water offers an abundant, clean fuel source, but it is challenging to produce photocatalysts that use the solar spectrum effectively. Many hydrogen-evolving photocatalysts are active in the ultraviolet range, but ultraviolet light accounts for only 3% of the energy available in the solar spectrum at ground level. Solid-state crystalline photocatalysts hav...
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The rate enhancements obtained by enzymes often require greater than 20 kcaVmol of stabilization that is specific to the transition state. Inspection of active sites suggests that enzymes often use multiple interactions with substrate groups undergoing charge rearrangement to help provide this preferential stabilization. We have analyzed the deprotonation, in DMSO, of benzoic acids with one or ...
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ژورنال
عنوان ژورنال: Science and Technology of Advanced Materials
سال: 2019
ISSN: 1468-6996,1878-5514
DOI: 10.1080/14686996.2019.1643259